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Formation of cyclohexanes in the palladium catalyzed reaction of ɛ-unsaturated cyano esters and congeners

✍ Scribed by D. Bouyssi; I. Coudanne; H. Uriot; J. Goré; G. Balme

Book ID
103408812
Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
214 KB
Volume
36
Category
Article
ISSN
0040-4039

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## Abstract The regioselectivity of the hydro‐alkoxycarbonylation of methyl acrylate, methacrylate, and crotonate catalyzed by [PdCl~2~L~2~] complexes (L = phosphine ligands) can be largely controlled by variation of the ligands. PPh~3~, promotes preferential carbonylation at the α‐position, wherea