Gas-phase thermochemical stabilities and structures of cluster ions F-(CF4) n and CF~-(CF4) ~ have been studied with a high-pressure mass spectrometer and ab initio calculations. The F-... CF a bonding energy is found to be only 6.4 kcal/mol. Its geometry is of an ion-dipole complex along an Sr~2 re
Formation of CF4− from CF4 clusters
✍ Scribed by Johannes Lotter; Alexander Kühn; Eugen Illenberger
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 261 KB
- Volume
- 157
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The pattern of the rotation-vibrational energy levels in isolated vibrational components of \(\mathrm{CF}_{4}\) has recently been described ( B. I. Zhilinskii et al.. J. Mol. Spectros: 160, 192-216, 1993) in terms of the semiclassical model for the rotation of molecules. The present paper discusses
Low-energy (~20 eV) electron attachment to condensed CF, is associated with the desorption of F-ions via dissociative electron attachment and dipohw dissociation. The present results are compared with the corresponding processes in the gas phase and from CF. clusters.