Formation of C49-TiSi2 in flash memories: a nucleation controlled phenomenon?

✍ Scribed by D. Mangelinck; P. Gas; T. Badéche; E. Taing; F. Nemouchi; C. Perrin-Pellegrino; M. Vuaroqueaux; S. Niel; P. Fornara; J.M. Mirabel; L. Fares; P.H. Albarede

• Publisher: Elsevier Science
• Year: 2003
• Tongue: English
• Weight: 605 KB
• Volume: 70
• Category: Article
• ISSN: 0167-9317
• DOI: 10.1016/s0167-9317(03)00435-0

✦ Synopsis

The formation of Ti silicides has been examined in flash memories with 0.25 mm linewidth by X-ray diffraction, scanning electron microscopy, and transmission electron microscopy. It has been observed that, after the first rapid thermal process and the selective metal etch, there is no silicide on the source and on a majority of drain contacts while C49-TiSi is found 2 on the gate. A pre-amorphisation implant increases drastically the formation of C49-TiSi in the drain zone while 2 modifications of annealing conditions have little impact. These results indicate that the formation of C49-TiSi is most likely 2 controlled by nucleation and that this nucleation is sensitive to both the width and the length of the reaction zone. The formation of a Ti rich silicide may play an important role in this nucleation by decreasing the driving force for the formation of C49-TiSi . Curiously enough, the formation of C49-TiSi appears thus as a major concern for the salicide process in flash 2 2 memories.