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Formation of biologically relevant carboxylic acids during the gamma irradiation of acetic acid

✍ Scribed by Alicia Negron-Mendoza; Cyril Ponnamperuma

Publisher
Springer Netherlands
Year
1976
Tongue
English
Weight
301 KB
Volume
7
Category
Article
ISSN
1573-0875

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Formation of phostonic acids during the
Formation of phostonic acids during the reduction of azidonucleosidephosphonic acids
✍ Michael Morr; Christel Kakoschke; Ludger Ernst πŸ“‚ Article πŸ“… 2001 πŸ› Elsevier Science 🌐 French βš– 204 KB

Reduction of 5%-azido-3%,5%-dideoxy-3%-(phosphorylmethyl)nucleosides, either with H 2 /Pd/C or with dithiothreitol, leads to cyclic phosphonate esters (phostonic acids) in addition to the desired 5%-amino compounds. The phostonic acids are obtained as the main products when a 20-fold excess of dithi