An alternative mechanism of mercaptoborane, BH,SH, formation is proposed for the reaction of BzHs with SH2. It involves concerted elimination of BH3 and H2 from the H2SB2Hs complex and the highest energy on the pathway relative to SH, + B2H6 is 27.4 kcal/mol at MP4(SDTQ)/6-31 +G(2d, p)//MP2(FULL)/6\
โฆ LIBER โฆ
Formation of [BH3]2- and [B2H6]2- From the Homogeneous Reduction of B2H6
โ Scribed by Godfroid, Robert A.; Hill, Tara G.; Onak, Thomas P.; Shore, Sheldon G.
- Book ID
- 126230332
- Publisher
- American Chemical Society
- Year
- 1994
- Tongue
- English
- Weight
- 229 KB
- Volume
- 116
- Category
- Article
- ISSN
- 0002-7863
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