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Dynamic electron transfers in B2H6and Cu(PH3)2(BH4)

✍ Scribed by Kenai Hori; Akitomo Tachibana


Publisher
Springer
Year
1986
Tongue
English
Weight
503 KB
Volume
70
Category
Article
ISSN
1432-2234

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An alternative mechanism of BH2SH format
✍ Alexander M. Mebel; Djamaladdin G. Musaev; Keiji Morokuma πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 411 KB

An alternative mechanism of mercaptoborane, BH,SH, formation is proposed for the reaction of BzHs with SH2. It involves concerted elimination of BH3 and H2 from the H2SB2Hs complex and the highest energy on the pathway relative to SH, + B2H6 is 27.4 kcal/mol at MP4(SDTQ)/6-31 +G(2d, p)//MP2(FULL)/6\