2,4,6-Ph3C6H2M (M Cu, Ag), Monomeric Cu1- and Ag1-Complexes with Coordination Number 1
✍ Scribed by Dipl.-Chem. Regine Lingnau; Prof. Dr. Joachim Strähle
- Publisher
- John Wiley and Sons
- Year
- 1988
- Tongue
- English
- Weight
- 139 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0044-8249
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Synthesis and crystal structure of 1,6-Bis-(N,Ndiethylaminothiocarbamoylimino)-1,6-diphenyl-2,5-dithiahexane are reported as well as those of its dimeric Ag I complex (as monotoluene adduct of the diperchlorate) and its tetrameric l-tetrabromo Ag I complex.
Blue crystals of Cu 2 (phen) 2 (H 2 O) 2 (C 5 H 6 O 4 ) 2 were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), glutaric acid and Na 2 CO 3 . The crystal structure (monoclinic, P2 1 /c (no. 14), a = 10.271(1), b = 10.595(1), c = 15.585(1) A Ê , b = 107.105(3)°,
## Abstract The first argentate salt of carborane anion, [{(CH~3~CN)~4~Ag~3~}{Ag(CB~11~I~5~Br~6~)~2~}]~__n__~, was prepared from K~2~[CB~11~I~5~Br~6~] and AgNO~3~ followed by recrystallization from acetonitrile. Single‐crystal X‐ray analyses indicate that the CB~11~I~5~Br~6~^2−^ dianion has a signi