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Formation of anionic palladium(0) complexes ligated by the trifluoroacetate ion and their reactivity in oxidative addition

✍ Scribed by Christian Amatore; Anny Jutand; Frédéric Lemaıˆtre; Jean Luc Ricard; Sebastian Kozuch; Sason Shaik

Book ID
108187862
Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
343 KB
Volume
689
Category
Article
ISSN
0022-328X

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Rate and Mechanism of the Reversible Formation of Cationic (η3-Allyl)- palladium Complexes in the Oxidative Addition of Allylic Acetate to Palladium(0) Complexes Ligated by Diphosphanes
✍ Christian Amatore; Sophie Gamez; Anny Jutand 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 155 KB 👁 1 views

The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h