Formation of an allyltin bond in η3-allyl(trichlorostannyl)palladium(II) complexes
✍ Scribed by Kazuyoshi Hirako; Yuki Miyamoto; Kiyomi Kakiuchi; Hideo Kurosawa
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 479 KB
- Volume
- 222
- Category
- Article
- ISSN
- 0020-1693
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📜 SIMILAR VOLUMES
The oxidative addition of the allylic acetate, CH 2 CH À CH 2 À OAc, to the palladium(0) complex [Pd 0 (P,P)], generated from the reaction of [Pd(dba) 2 ] with one equivalent of P,P (P,P dppb 1,4-bis(diphenylphosphanyl)butane, and P,P dppf 1,1'-bis(diphenylphosphanyl)ferrocene), gives a cationic (h
## Abstract The complex cations [M(η^3^‐R~2~All)(PPFPz{3‐__t__Bu})]^+^ (M = Pd^II^, R~2~All = 1,3‐diphenylallyl, 1,3‐dicyclohexylallyl, indenyl; M = Pt^II^, R~2~All = 1,3‐diphenylallyl; PPFPz‐{3‐__t__Bu} = 3‐__tert__‐butyl‐1‐{1‐[2‐diphenylphosphanyl‐ferrocenyl]ethyl}‐1__H__‐pyrazole)have been prepa