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Formation of a “meso-Helicate” by Self-Assembly of Three Bis(catecholate) Ligands and Two Titanium(IV) Ions

✍ Scribed by Dr. Markus Albrecht; Dr. Sirpa Kotila


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
673 KB
Volume
34
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES


Self-Assembly of a Triple-Strandedmeso-H
✍ Albrecht, Markus ;Riether, Cyrill 📂 Article 📅 1996 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 389 KB

## Abstract 1,3‐Bis(5′‐methyl‐2,2′‐bipyrid‐5‐yl)propane (3) can be synthesized by a two‐step procedure starting from 3‐picoline (1). In a spontaneous self‐assembly process 3 forms the binuclear triple‐stranded __meso__‐helicate [(3)~3~Fe~2~][PF~6~]~4~ on addition of iron(II) salts. The (Λ,Δ) struct