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Formation of a dinaphthanthracene by a stilbene-like photocyclization

✍ Scribed by Frank B. Mallory; Clelia W. Mallory; Stephanie E. Sen Loeb

Book ID
104222438
Publisher
Elsevier Science
Year
1985
Tongue
French
Weight
255 KB
Volume
26
Category
Article
ISSN
0040-4039

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✦ Synopsis

Photo$ycfization of 1,3-bis[2-(Z-naphthyl)vinyl]benzene leads regioselectively to dinaphth[l,2-a:2 ,l -J,]anthracene without the need for a blocking bromine substituent at C-2 in the starting material as assumed previously by other workers.

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Phenacenes: A Family of Graphite Ribbons. Part 1. Syntheses of Some (7) Phenacenes by Stilbene-Like Photocyclizations. -By employing stilbene-like photocyclizations, the synthesis of the up to now largest known phenacenes (VII) and (XI) containing seven rings is described. The parent system (VII) i