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Formation of 4-methylthio-2-phenyl-1-butene derivatives by the reaction of β-hydroxy-β-phenylsulfonium salt with base

✍ Scribed by Shinzo Kano; Tsutomu Yokomatsu; Shiroshi Shibuya


Publisher
Elsevier Science
Year
1978
Tongue
French
Weight
119 KB
Volume
19
Category
Article
ISSN
0040-4039

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Formation of a reasonably stabilized tri
✍ Tatsuya Shono; Manabu Ishifune; Osamu Ishige; Hiroshi Uyama; Shigenori Kashimura 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 260 KB

A reasonably stabilized trichloromethyl anion (TCMA) was formed by the reaction of chloroform with an electrogenerated base prepared by the electroreduction of Zpyrrolidone, and the addition of this TCIvIA to a$unsaturated esters gave the corresponding B-trichloromethyl esters in good yields.