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Formation of 1,2-dioxacyclohexanes by the reaction of alkenes with tris(2,4-pentanedionato)manganese(III) or with β-ketocarbonyl compounds in the presence of manganese(III) acetate

✍ Scribed by Shin-ichi Tategami; Takashi Yamada; Hiroshi Nishino; James D. Korp; Kazu Kurosawa


Publisher
Elsevier Science
Year
1990
Tongue
French
Weight
158 KB
Volume
31
Category
Article
ISSN
0040-4039

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Catalytic oxidation of 4-piperidone-3-ca
✍ Ryoukou Kumabe; Hiroshi Nishino; Mikio Yasutake; Van-Ha Nguyen; Kazu Kurosawa 📂 Article 📅 2001 🏛 Elsevier Science 🌐 French ⚖ 77 KB

The manganese(III) acetate-catalyzed cycloperoxidation of 4-piperidone-3-carboxylates with 1,1-disubstituted alkenes is described. The 4-piperidone-3-carboxylates reacted with 1,1-disubstituted alkenes in the presence of a catalytic amount of manganese(III) acetate in air at 23°C to give 1-hydroxy-8