𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Formation of 1,3-Diphosphacyclobutadiene Complexes from Phosphaalkynes and Their Coordination Behavior

✍ Scribed by Rummel, Eva-Maria; Eckhardt, Maria; Bodensteiner, Michael; Peresypkina, Eugenia V.; Kremer, Werner; Gröger, Christian; Scheer, Manfred

Book ID
125828720
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
415 KB
Volume
2014
Category
Article
ISSN
1434-1948

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Coordination Chemistry of 1,3-Bis(2-pyri
Coordination Chemistry of 1,3-Bis(2-pyridylimino)- and 1,3-Bis(2-thiazolylimino)soindole Copper Complexes: Investigation of Their Catalytic Behavior in Oxidation Reactions
✍ Markus B. Meder; Lutz H. Gade 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 182 KB

## Abstract The copper complexes [Cu(4‐MeBPI)(OAc)] (**4**), [Cu(4‐Me‐10‐__t__BuBPI)(OAc)] (**5**) and [Cu(BTI)(OAc)] (**6**) [BPI = 1,3‐bis(2‐pyridylimino)isoindole, BTI = 1,3‐bis(2‐thiazolylimino)isoindole] were prepared by reaction of the protio ligands with copper(II) acetate. Compounds **4** a

Novel Reactions of Phosphaalkynes in the
Novel Reactions of Phosphaalkynes in the Coordination Sphere of tert-Butylimido- vanadium(V) Complexes: A Simple Synthesis of 3-Aza-1,2,4,6-tetraphosphaquadricyclanes and 1,3,5-Triphosphabenzenes
✍ Frank Tabellion; Anja Nachbauer; Stefan Leininger; Christoph Peters; Fritz Preus 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 107 KB 👁 2 views

A small variation in the vanadium reagent leads to a completely different product: The cyclooligomerization of phosphaalkynes 2 with tBuN=VCl ⋅DME (DME=1,2-dimethoxyethane) proceeds with incorporation of the imido fragment to give the azatetraphosphaquadricyclanes 1. In contrast, with the correspond