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Formation constant and stoichiometry of the acetonitrile:18-crown-6 complex by nuclear magnetic resonance, raman and infrared spectroscopy

✍ Scribed by Harvey S. Gold; Michael R. Rice


Book ID
118993602
Publisher
Elsevier Science
Year
1982
Tongue
English
Weight
394 KB
Volume
29
Category
Article
ISSN
0039-9140

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We r port resolution of individual carbon environments of 18-crown-6 ether and its KNCS complex using I5 C CPMAS nuclear magnetic resonance spectroscopy at low temperature. The importance of torsional angle effects in determining chemical shifts in these solids is discussed.