Formation and synthetic utility of benzyl- and phenyl-cyclopentadienylthallium
β Scribed by Poonam Singh; Marvin D. Rausch; Thomas E. Bitterwolf
- Publisher
- Elsevier Science
- Year
- 1988
- Tongue
- English
- Weight
- 858 KB
- Volume
- 352
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The structure of the product obtained by reacting the 1,4-dihydropyridine 6 with pyridinium bromide perbromide has been confirmed by NMR spectroscopy as the I-bromomethyl derivative 7 and its reaction with a range of nucleophiles has been studied.
Electrolysis of the following salts in various solvents at an aluminum cathode gave benzene as the major cleavage product: trimethylanilinium nitrate, trimethylanilinium methoxide, triethylanilinium nitrate and triethylanilinium methoxide. The rate of formation of benzene was studied in several case