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Formation and structure of a Pd(I) complex: The crystal structure of (C5H8N2S)4Pd(II)Cl2·H2O and the ESR study of the X-irradiated single crystal

✍ Scribed by P. Aarrizabalaga; G. Bernardinelli; M. Geoffroy; P. Castan; F. Dahan

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 613 KB
Volume: 124
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)85074-6

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✦ Synopsis

The crystal structure of tetrakis(tetrahydro-lH-pyrimidine-2-thione)palladium(II) dichloride monohydrate has been determined X-irradiation of a single crystal, at liquid-nitrogen temperature, leads to formation of a paramagnetic species whose ESR study has been performed at 77 K. The g and to5Pd-hyperfine tensors have been obtained. Their eigenvalues are consistent with the trapping of a d9 ion. Comparison of the eigenvectors with the crystallographic bond directions shows that the pammagnetic species results from the reduction of Pd(I1) to Pd(I) which remains at the center of a square formed by four sulphur atoms.

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