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Formation and structure of a complex of sucrose with cobalt(III)bis(phenanthroline)

✍ Scribed by José Parada; Sergio Bunel; Carmen Ibarra; Guillermo Larrazabal; Exequiel Moraga; Nicholas D Gillitt; Clifford A Bunton


Book ID
108309270
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
166 KB
Volume
333
Category
Article
ISSN
0008-6215

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Complexes of cobalt(III) with d-fructose
✍ Exequiel Moraga; Sergio Bunel; Carmen Ibarra; Andrei Blaskó; Clifford A. Bunton 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 816 KB

D-Fructose and 1,10-phenanthroline form complexes with Co(III). Configurations about Co(III) are assigned from the CD and ORD spectra of the separated A and A diastereomers, and A strongly predominates in the mixture. Most of the 1H NMR signals of the complexes are shifted strongly upfield, relative