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Formation and structural characterization of a sterically protected silicic acid diester

✍ Scribed by Stefan Spirk; Martin Nieger; Gerald N. Rechberger; Rudolf Pietschnig

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 167 KB
Volume: 20
Category: Article
ISSN: 0268-2605
DOI: 10.1002/aoc.1117

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✦ Synopsis

Abstract

The hydrolytic stability of the sterically protected dichlorosilane (Mes*O)~2~SiCl~2~ was investigated. The resulting products have been identified by electrospray mass spectrometry and, in the case of (Mes*O)~2~Si(OH)~2~, the crystal structure was obtained. Copyright © 2005 John Wiley & Sons, Ltd.

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We thank the European Commission through the HYDROCHEM program (contract HPRN-CT-2002-00176) for support of this work. M.B. thanks the Spanish Ministerio de Educación y Ciencia for a postdoctoral fellowship.