Fused I ,3-benzothiaphospholes 2 (cis-2,6,1 O-trimethyl-[1 ,3]benzothiaphospholo [2,3-bl[l, 3lbenzothiaphosphole) reacts with H 2 0 2 and S8, giving the corresponding oxide and sulfide, respectively. The reactions of 2 with ðyl azodicarboxylate (DEAD)/ catechol or DEAD/cl-aminophenol, o-azidophen
Formation and Reactivity of 1,3-Dialuminium Alkanes
β Scribed by A. Stefani; P. Pino
- Book ID
- 102249444
- Publisher
- John Wiley and Sons
- Year
- 1972
- Tongue
- German
- Weight
- 333 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0018-019X
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β¦ Synopsis
Abstract
The formation of 1,3βdialuminium alkanes by autoβaddition or by hydroβalumination of methallylβaluminium derivatives is reported. Some aspects of their thermal decomposition and of their reactivity are discussed.
π SIMILAR VOLUMES
models shows that the van der Waals repulsions to be overcome in each case are comparable.
Reacting 2-lithio-1,3-dithioles with 1,3-dithiolium salts results in formation of both symmetrical and unsymmetrical tetrathiafulvalenes. The symmetrical tetra-thiafulvalenes are probably formed via a carbene intermediate which is generated by loss of an hydride from the 2-lithio-1,3dithioles.