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Formation and Characterization of the Indium Hydride Molecules H 2 InCl and HInCl 2 : Matrix Isolation and Quantum Chemical Studies

✍ Scribed by Himmel, Hans-Jörg; Downs, Anthony J.; Greene, Tim M.


Book ID
126861421
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
108 KB
Volume
122
Category
Article
ISSN
0002-7863

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Aqua and aqua-chloride complexes of Al III and In III have been isolated from aqueous solutions and structurally characterized by X-ray analysis as supramolecular adducts with cucurbituril. Using this approach, trans-[InCl 2 (H 2 O) 4 ] + and trans-[InCl 4 (H 2 O) 2 ] -species were detected and isol