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Formal Total Synthesis of (—)-Morphine by Cuprate Conjugate Addition

✍ Scribed by Prof. Dr. Johann Mulzer; Dr. Gerd Dürner; Dipl.-Chem. Dirk Trauner

Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
385 KB
Volume
35
Category
Article
ISSN
0044-8249

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📜 SIMILAR VOLUMES

ChemInform Abstract: The Phenanthrenone
ChemInform Abstract: The Phenanthrenone Approach to Opium Alkaloids: Formal Total Synthesis of Morphine by Sigmatropic Rearrangement.
✍ J. MULZER; J. W. BATS; B. LIST; T. OPATZ; D. TRAUNER 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 1 views

The Phenanthrenone Approach to Opium Alkaloids: Formal Total Synthesis of Morphine by Sigmatropic Rearrangement. -Eschenmoser-Claisen rearrangement of alcohol (II) and ring closure reaction of epoxide (VII) to give the desired E-ring are the key steps in the preparation of the morphine synthon (VII