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ChemInform Abstract: The Phenanthrenone Approach to Opium Alkaloids: Formal Total Synthesis of Morphine by Sigmatropic Rearrangement.

✍ Scribed by J. MULZER; J. W. BATS; B. LIST; T. OPATZ; D. TRAUNER

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

The Phenanthrenone Approach to Opium Alkaloids: Formal Total Synthesis of Morphine by Sigmatropic Rearrangement.

-Eschenmoser-Claisen rearrangement of alcohol (II) and ring closure reaction of epoxide (VII) to give the desired E-ring are the key steps in the preparation of the morphine synthon (VIII). -(MULZER,

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