Formal Total Synthesis of (.+-.)-Martinellic Acid.
β Scribed by Yong He; Remond Moningka; Carl J. Lovely
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 10 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
## Abstract **The right bicycle**: A concise formal synthesis of platencin was based on an efficient oxygenβmediated palladiumβcatalyzed cycloalkenylation of **1** to form a bicyclo[3.2.1]octane, and a deoxygenative rearrangement of tosylhydrazone **2** to construct the bicyclo[2.2.2]octane **3**.
## Abstract **Der richtige Bicyclus**: Die effiziente sauerstoffvermittelte palladiumkatalysierte Cycloalkenylierung von **1** zu einem Bicyclo[3.2.1]octan und die desoxygenierende Umlagerung des Tosylhydrazons **2** zum Bicyclo[2.2.2]octan **3** sind wesentliche Schritte der Synthese der Kernstruk