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Formal total synthesis of (±)-magellanine

✍ Scribed by Miyuki Ishizaki; Yuka Niimi; Osamu Hoshino


Book ID
104254130
Publisher
Elsevier Science
Year
2003
Tongue
French
Weight
159 KB
Volume
44
Category
Article
ISSN
0040-4039

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✦ Synopsis


Formal total synthesis of magellanine is described. Key features in the synthesis were stereoselective Ireland-Claisen rearrangement and intramolecular Pauson-Khand reaction of exo-cyclic enynes.


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Formal total synthesis of (+)-boronolide
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+)-Boronolide, a polyacetoxy natural product having four contiguous asymmetric centers has been synthesized from d-mannitol.