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Formal Total Synthesis of (.+-.)-Magellanine.

✍ Scribed by Miyuki Ishizaki; Yuka Niimi; Osamu Hoshino


Publisher
John Wiley and Sons
Year
2003
Weight
57 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract **The right bicycle**: A concise formal synthesis of platencin was based on an efficient oxygen‐mediated palladium‐catalyzed cycloalkenylation of **1** to form a bicyclo[3.2.1]octane, and a deoxygenative rearrangement of tosylhydrazone **2** to construct the bicyclo[2.2.2]octane **3**.