Formal [1,3] rearrangement of 2-furylmethyl and 2-thienylmethyl vinyl ethers
โ Scribed by Namnsivayam Palani; Kalpattu Kuppusamy Balasubramanian
- Book ID
- 103400818
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 193 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0040-4039
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๐ SIMILAR VOLUMES
Allyl vinyl ethers containing an acceptor function in the 2-position are useful substrates for the Lewis acid-catalyzed Claisen rearrangement. The first synthesis of acyclic 2-(1,3-oxazolin-2-yl)-substituted allyl vinyl ethers is reported. The Lewis acid catalyzed Claisen rearrangement of these ally
Unusual [ 1,3]-rearrangement of aryl2-halocyclohexenylmethyl ethers promoted by trifluoroacetic acid was observed. Products due to Claisen rearrangement were not formed.
The thiazetidines (l\_) and ( 2) undergo a novel and high yielding rearrangement