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Novel catalytic rearrangements of 2-vinyl-1,3-thiazetidines

✍ Scribed by Nigel K. Capps; Gareth M. Davies; Douglas W. Young


Book ID
104241428
Publisher
Elsevier Science
Year
1984
Tongue
French
Weight
201 KB
Volume
25
Category
Article
ISSN
0040-4039

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✦ Synopsis


The thiazetidines (l_) and ( 2) undergo a novel and high yielding rearrangement


πŸ“œ SIMILAR VOLUMES


Properties and reactions of substituted
✍ Schwenkkraus, Peter ;Otto, Hans-Hartwig πŸ“‚ Article πŸ“… 1994 πŸ› John Wiley and Sons 🌐 English βš– 771 KB

## Abstract β‐Sultam‐3‐acetic acid ester 3 prepared from __rac‐S__‐benzyl‐β‐homocysteine is alkylated with bromoacetates yielding diacetates 9 which are transformed into the phenylthio esters 11. The thiazinanone derivatives 12 are obtained from 11 by rearrangement with lithium bis(trimethylsilyl)a