Form of the coordination sphere of copper(II) halide complexes with nitroanilines
β Scribed by A. T. Pilipenko; L. L. Shevchenko; G. N. Pshinko; D. A. Stakhov
- Publisher
- Springer US
- Year
- 1979
- Tongue
- English
- Weight
- 360 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0021-9037
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Complexes of the type M(4-F3-NA),X, . mHIO (where M = Cu(II), Ni(II), Co(H); 4-F3-NA = 4-fluoro, 3-nitroaniiine; (n = l-4; X = Cl, Br, SCN, CIO,; m = 04) have been studied by i.r. and electronic spectroscopy, magnetic and conductivity measurements. The ligand behaves as monodentate O-bonded. All the
Tetraaquabis(o-sulfobenzimidato-N)copper(II) reacts with neutral N-heterocycles to form complexes in which the o-sulfobenzimide (saccharin) entity interacts directly with the copper atom (through either the endocyclic nitrogen atom or the exocyclic oxygen atom) or indirectly, through coordinated wat