Complexes of copper(II), nickel(II) and cobalt(II) with 4-fluoro, 3-nitroaniline
β Scribed by M. Biddau; G. Devoto; M. Massacesi; R. Pinna; G. Ponticelli
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 326 KB
- Volume
- 37
- Category
- Article
- ISSN
- 1386-1425
No coin nor oath required. For personal study only.
β¦ Synopsis
Complexes of the type M(4-F3-NA),X, . mHIO (where M = Cu(II), Ni(II), Co(H); 4-F3-NA = 4-fluoro, 3-nitroaniiine; (n = l-4; X = Cl, Br, SCN, CIO,; m = 04) have been studied by i.r. and electronic spectroscopy, magnetic and conductivity measurements. The ligand behaves as monodentate O-bonded. All the compounds are high spin and nonconductors except of the perchlorato derivatives, and have different stereochemistries. CONCLUSIONS M. BIDDAU et al.
π SIMILAR VOLUMES
## ALastract -Coordmatlon compounds formed by the interaction of hexamethylenetetramme (Hmta), a wtentiallv tetradentate heand, with Mn(I1). Co(I1). TWII). Cu(I1). Zn(I1) and Cd(I1) thmcvanates have been prepared and character& from ih& elem&tal analyses, magnetic sus&ptlbWl&, electronic and I r s
The properties of pilocarpine as a ligand toward the halides of cobalt(II), nickel(II), copper(II), and zinc(II) were investigated. Pilocarpine behaved as a monodentate ligand, giving rise to compounds with the general formula methyl(pilocarpine)2X2. The coordinating geometry at the metal ion was ps