Flüssigphasenoxydation von Cyclohexen in Gegenwart von Kombinationen von Verbindungen verschiedener Metalle

✍ Scribed by Dr. H.-F. Boeden; Prof. Dr. J. Dahlmann; Dr. H.-J. Hamann; Dr. E. Höft

• Publisher: John Wiley and Sons
• Year: 1982
• Tongue: English
• Weight: 688 KB
• Volume: 324
• Category: Article
• ISSN: 1615-4150
• DOI: 10.1002/prac.19823240405

✦ Synopsis

The Liquid Phase Oxidation of Cyclohexene in Presence of Combinations of Compounds of Different Metals

The oxidation of cyclohexene (1) with molecular oxygen in chlorobenzene solution at 80°C has been studied using cobalt, manganese and copper compounds, respectively in combination with molybdenum complexes. The selectivity has been determined of cyclohex‐2‐en‐1‐hydroperoxide (2), epoxycyclohexane (3), cyclohex‐2‐en‐1‐ol (4), cyclohex‐2‐en‐1‐one (5), 2,3‐epoxy‐cyclohexane‐1‐ol (6) and cyclohexane‐1,2‐diol (7), formed from reacted 1. Investigation of the consecutive reactions showed that 3 and especially 4 can react in different ways and moreover 4 inhibits the oxidation of 1. From these results conclusions were drawn on the mechanism of oxidation of 1.