A fluorometric-calorimetric fluorescamine analyzer was successfully utilized for the analysis of a series of actinomycin hydrolysates containing N-methylamino acids, proline. and proline derivatives. An explanation is proposed for the low threonine values consistently observed in the analysis of act
Fluorometric analysis of Nα-methylamino acids using fluorescamine
✍ Scribed by Arthur M. Felix; Gene Terkelsen
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 484 KB
- Volume
- 60
- Category
- Article
- ISSN
- 0003-2697
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## Abstract In the polymerizations of alanine, γ‐ethyl glutamate, and leucine __N__‐carboxyanhydrides (NCA's) initiated by tertiary amines and some secondary amines such as __N__‐methyl‐L‐alanine dialkylamide, a stereoselectivity was observed: the polymerization rates of L‐ and D‐NCA's were identic