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Fluorocarbon ortho esters. Synthesis and characterization of 1,4-bis(trifluoromethyl)-2,6,7-trioxabicyclo[2.2.2]octane

✍ Scribed by Talbott, Richard L.


Book ID
125943648
Publisher
American Chemical Society
Year
1967
Tongue
English
Weight
333 KB
Volume
32
Category
Article
ISSN
0022-3263

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The preparation of novel 3-(4-methyl-2,6,7-trioxabicyclo[2.2.2]octyl)-A2-isoxazolines 2 via nitrile oxide cycloaddition chemistry is described. The target compounds were produced in moderate to good yields using only 2.2 equivalents of alkene and without the need for slow addition of reagents. Cyclo