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4-Hydroxymethyl-1-phospha-2,6,7-trioxabicyclo[2.2.2]octane 1-Sulfide and Derived Compounds

✍ Scribed by Rätz, Rudi; Sweeting, Orville J.


Book ID
127207286
Publisher
American Chemical Society
Year
1965
Tongue
English
Weight
597 KB
Volume
30
Category
Article
ISSN
0022-3263

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✍ Stewart K. Richardson; Alwarsamy Jeganathan; David S. Watt 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 202 KB

The metalation of (El-l-(2-chlorovinyl)-or (E)-1-(2-bromovinyl)-4-methyl-2,6,7-trioxabicyclo[2.2.2]octane with tert-butyllithium produced an unsaturated homoenolate anion equivalent which intercepted alkyl halides, aldehydes, ketones, and lactones to afford 8-alkylated or 8-acylated orthoesters, whi