Fluoroalkylated α,β-Unsaturated Imines as Synthons for the Preparation of Fluorinated Triazinane-2,4-diones and Dihydropyrimidin-2(1 H )-ones
✍ Scribed by Fernández de Trocóniz, Guillermo; Ochoa de Retana, Ana M.; Rubiales, Gloria; Palacios, Francisco
- Book ID
- 121864277
- Publisher
- American Chemical Society
- Year
- 2014
- Tongue
- English
- Weight
- 944 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
## Abstract A simple, mild and convenient method for the synthesis of vinylogous fluoroalkylated ‐amino esters (IV) and (VI) by 1,2‐addition of enolates to fluoroalkylated α,β‐unsaturated imines is described.
we describe a convenient and general method for the preparation of 2,3-dihydro-2-niuo-3-phenyl-4H-furo[3,2-c][l]~~opy~-4-ones from cl-hydroxycoumarin and (2-chloro-2-nitroethenyl)benzenes in the presence of potassium fluoride. Using the same starting materials and by replacing potassium fluoride wit