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ChemInform Abstract: Fluoroalkylated α,β-Unsaturated Imines: Efficient and Versatile Substrates for the Synthesis of Fluorinated Vinylogous β-Amino Esters and 3,4-Dihydropyridin-2-ones.

✍ Scribed by Francisco Palacios; Ana M. Ochoa de Retana; Sergio Pascual; Guillermo Fernandez de Troconiz; Jose M. Ezpeleta

Publisher: John Wiley and Sons
Year: 2011
Weight: 40 KB
Volume: 42
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201114081

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✦ Synopsis

Abstract

A simple, mild and convenient method for the synthesis of vinylogous fluoroalkylated ‐amino esters (IV) and (VI) by 1,2‐addition of enolates to fluoroalkylated α,β‐unsaturated imines is described.

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Fluoroalkylated α,β-Unsaturated Imines:

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