Fluorine substituent effects on bio-methylenation of olefinic fatty acids
β Scribed by Peter H. Buist; Judy M. Findlay
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- French
- Weight
- 238 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0040-4039
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Fluorine, the heterosubstituent par excellence, which can have a stronger impact on the reactivity in its vicinity than any other element, may serve as a crucial test of any model of the origin and transmission of electronic effects. To what extent fluoro substituents in organic compounds (A-H) incr
Introduction of a fluorine substituent into an aromatic ring of [2.2]paracyclophane causes distinct shielding and deshielding effects at the anti -and syn-protons, respectively, of the adjacent bridge methylene group. A recent contradictory claim in the literature was disproved by 2D H,H-NOESY, long