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Fluorine chemistry and electrochemistry - fluorine evolution, graphite intercalation compounds of fluorine and battery applications

โœ Scribed by Nobuatsu Watanabe; Hidekazu Touhara; Tsuyoshi Nakajima

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
67 KB
Volume
35
Category
Article
ISSN
0022-1139

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Graphite intercalation compound of magne
Graphite intercalation compound of magnesium fluoride and fluorine
โœ T. Nakajima; M. Kawaguchi; N. Watanabe ๐Ÿ“‚ Article ๐Ÿ“… 1982 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 501 KB

A graphite intercalation compound of C,F(MgF& was prepared under a fluorine atmosphere of 1 atm at temperatures of 20-350ยฐC. The 1st stage compound has the identity period of 9.3-9.4& ESCA and @F NMR spectra indicate that the chemical interaction of intercalated fluorine with carbon is similar to th

Electrochemical behavior of graphite int
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Ternaryintercalationcompounds,C,F(AlF,),andC,F(MgF,),containingactivefluorineatoms adsorbed on carbon Iavers of host tzraohite were used as a cathode material of lithium cell. The discharge potentials are 2.8-2.5 v at current densities 40400 PA cm-', being higher than that for graphite fluoride belo

Structure of fluorine-graphite intercala
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The fluorination of highly oriented pyrolytic graphite (HOPG), powdery and flaky natural graphites, and carbon fiber (P 100) has been performed in a fluorine atmosphere with HF gas (5.3 x 103-4.8 x lo4 Pa), or by flowing fluorine gas in anhydrous liquid hydrogen fluoride (AHF) at ambient temperature

Preparation, structure, and electrical c
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The rate of fluorine intercalation in graphite is larger in the present system than in other metal fluorides examined previously. X-ray diffraction data indicate that C,F belongs to a hexagonal system with a superlattice of a, = 2a, in the ab plane, accompanying some amount of a bi-intercalation pha