Fluorinated allylic alcohols as building blocks
β Scribed by Thomas Allmendinger; Christoph Angst; Heinrich Karfunkel
- Book ID
- 103183203
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 517 KB
- Volume
- 72
- Category
- Article
- ISSN
- 0022-1139
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## Abstract For Abstract see ChemInform Abstract in Full Text.
2,2,2-Trifluoroacetimidoyl chlorides 1 are much more stable than the corresponding nonfluorinated chlorides because of the deactivation for hydrolysis by the strong electronwithdrawing fluorine atom and thus useful as synthetic blocks. They react smoothly with nucleophilics such as Grignard reagent
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