Fluoride solutions in carboxylic acids: Ab initio calculations incorporating solvation effects, and infrared studies: Chem. Phys. Letters 84 (1981) 593. Received 8 April 1982

Fluoride solutions in carboxylic acids:

Fluoride solutions in carboxylic acids: ab initio calculations incorporating solvation effects, and infrared studies

✍ John Emsley; Jeremy Lucas; Richard E. Overill 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 416 KB

Solutions of KF UI gtac& acehc acd mvolve three hydrogen-bonded species III equdibnum 2CH#Z02HF-\* HF; + H(CH3C02); (1) Ab mitlo calculahons. on the fomuc and system, show that the isolated Ion HCOzHF-is tile most . stable speaes However with a solvent sphere model the right-hand suie of (1) IS favo