Fluoride solutions in carboxylic acids: ab initio calculations incorporating solvation effects, and infrared studies

✍ Scribed by John Emsley; Jeremy Lucas; Richard E. Overill

• Book ID: 103017582
• Publisher: Elsevier Science
• Year: 1981
• Tongue: English
• Weight: 416 KB
• Volume: 84
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(81)80415-0

✦ Synopsis

Solutions of KF UI gtac& acehc acd mvolve three hydrogen-bonded species III equdibnum 2CH#Z02HF-* HF; + H(CH3C02); (1) Ab mitlo calculahons. on the fomuc and system, show that the isolated Ion HCOzHF-is tile most . stable speaes However with a solvent sphere model the right-hand suie of (1) IS favoured.