The infrared absorption specmum of the hydrogen-bonded water dimer, (HzO)z, formed in a supersonic eapansion, was recorded in the region of the OH stretch by monitor@ the predissociation resulting from the absorption of the radiation. The conditions were such that there was minimal contribution to t
Fluorescence spectra of fluorobenzene cations excited in a supersonic molecular beam
β Scribed by R.P. Tuckett
- Book ID
- 103663793
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 874 KB
- Volume
- 58
- Category
- Article
- ISSN
- 0301-0104
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Triatomic van der Waals complexes of mercury have been observed in a supersonic expansion beam crossed with a laser beam to produce excitation and fluorescence spectra. The expansion beam consisting of mercury and a (noble) carrier gas (RG) was excited in three separate spectral regions: in the vici
Flnon'sccncc cscitution spectra of ~cokly bound con~plcscs formed between benzene and various solvent n~oleculcs prcparcd in B supersonic free jet ktvc been observed. The intcrmoleculsr interaction and the structure of the conqGcses 11iwc been discussrd.
Laser-induced resonant two-photon ionization of toluene and fluorobenzene cooled in a seeded supersonic expansion of Ar, combined with time-of-flight mass spectrometry. reveal the isotopic shifts of the vibronic origin of the 'B7 -'A,