Fluorescence quenching as a tool for studies of rates of intramolecular encounters
β Scribed by J.A. Nairn; C.L. Braun; P. Caluwe; M. Szwarc
- Publisher
- Elsevier Science
- Year
- 1978
- Tongue
- English
- Weight
- 389 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
Time-resolved study of intramolecular fluorescence quenching in a 9,lO~imethyhnrthracene derivative u+hich has a CBr3 group attached to it by 3 chain composed of 11 atoms provides the rate of in;ramolecular collision between these two groups since it is shown that the bimolecdar quenching of the fluorescence of 9, IOdimethylanthracene by trrbromoacetic acid or by its ester takes place on every encounter.
π SIMILAR VOLUMES
## Radiative lifetimes and quenching rates habe been measured for rotational levels of CS A 'r~(v = 0) throughout the region of perturbation by the a' 3p -(u = 10) state. The measured lifetimes reflect the extent of mi..ing with the a' 3~ state and from the unperturbed value oft = 171 + 10 ns the
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