The fluorescence anisotropy of a general rigid body is formally the sum of five exponentials. We show that, to a high degree of approximation, there are relationships between the five time constants. As we define the time constants here, T I 2 75, ~2 z 73, and ~1 -l + 3 ~4 -l = 4 T 2 -l . In practi
✦ LIBER ✦
Fluorescence anisotropy and rotational diffusion of polyene-like molecules in solution
✍ Scribed by H.-J. Egelhaaf; L. Lüer; A. Tompert; P. Bäuerle; K. Müllen; D. Oelkrug
- Book ID
- 117537291
- Publisher
- Elsevier Science
- Year
- 2000
- Tongue
- English
- Weight
- 215 KB
- Volume
- 115
- Category
- Article
- ISSN
- 0379-6779
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## B y J . G l o w a c k i With 1 Figure A bstrae t The aim of this paper is to show that PERRIN'S formula for the fluorescence emission anisotropy fits very well the experimental results of rotational depolarization for fluorescein in glycerin if the diffusion coefficient of thermal rotation, def
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