Rotation Mechanism of Molecules and Fluorescence Depolarization of Liquid Solutions

✍ Scribed by J. Glowacki

• Publisher: John Wiley and Sons
• Year: 1964
• Tongue: English
• Weight: 169 KB
• Volume: 469
• Category: Article
• ISSN: 0003-3804
• DOI: 10.1002/andp.19644690104

✦ Synopsis

B y J . G l o w a c k i

With 1 Figure A bstrae t The aim of this paper is to show that PERRIN'S formula for the fluorescence emission anisotropy fits very well the experimental results of rotational depolarization for fluorescein in glycerin if the diffusion coefficient of thermal rotation, defined by D = D, exp (-E / k T ) , is introduced. 1) J. FRENKEL, Kinetic theory of liquids, Oxford, 1916. ' ) R. BAUER, 2. Naturforschg. 188, 718 (19G3). 5) J. HEVESI, Acta Phys. et Chem. Szeged 8,lG (19G2).

Gda.ns k (Poland), Physics Department., High School of Pedagogy.

Bei der Rcdaktion eingegangen am 22. Oktober 1963.