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Flow-injection extraction spectrophotometric determinatin of chromium(VI) with the benzyltributylammonium cation

โœ Scribed by S.A. Barakat; D.Thorburn Burns; Michael Harriott


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
309 KB
Volume
272
Category
Article
ISSN
0003-2670

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โœฆ Synopsis


Chrommm(V1) can be determmed spectrophotometncally at 365 nm after flow-mjectlon extraction mto chloroform of the ion associate benzyltr~butyhunmonmm dlchromate The tamer stream was distilled water, merged with 10 M sulphunc acid solution, the reagent stream was 0 5% (w/v) benzyltnbutylammonmm chlonde solution The mJectlon rate was 20 h-' The cahbratlon graph was lmear up to 20 pg ml-' and the detection hnut (3 X baseline noise) was 0 5 pg ml-' CrWI) based on 25Oql lwectlon volumes The system has been applied to the determination of chronuum m steels


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Flow-injection extraction-spectrophotome
โœ D. Thorburn Burns; S.A. Barakat; M. Harriott; M.S. El-Shahawi ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 201 KB

A flow-injection manifold has been developed for the spectrophotometric determination of manganese(VII) at 548 nm after extraction into chloroform of the ion-associate, benzyltributylammonium permanganate. The carrier stream was a pH 6 buffer containing 10% (w/v) ammonium fluoride and the reagent st