A flow-injection manifold has been developed for the spectrophotometric determination of manganese(VII) at 548 nm after extraction into chloroform of the ion-associate, benzyltributylammonium permanganate. The carrier stream was a pH 6 buffer containing 10% (w/v) ammonium fluoride and the reagent st
โฆ LIBER โฆ
Flow-injection extraction spectrophotometric determinatin of chromium(VI) with the benzyltributylammonium cation
โ Scribed by S.A. Barakat; D.Thorburn Burns; Michael Harriott
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 309 KB
- Volume
- 272
- Category
- Article
- ISSN
- 0003-2670
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โฆ Synopsis
Chrommm(V1) can be determmed spectrophotometncally at 365 nm after flow-mjectlon extraction mto chloroform of the ion associate benzyltr~butyhunmonmm dlchromate The tamer stream was distilled water, merged with 10 M sulphunc acid solution, the reagent stream was 0 5% (w/v) benzyltnbutylammonmm chlonde solution The mJectlon rate was 20 h-' The cahbratlon graph was lmear up to 20 pg ml-' and the detection hnut (3 X baseline noise) was 0 5 pg ml-' CrWI) based on 25Oql lwectlon volumes The system has been applied to the determination of chronuum m steels
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