On-line electrochemical derivatization combined with diode-array u.v./visible detection in flowinjection systems greatly enhances the selectivity. The system is applied for the determination of the antineoplastic agents etoposide (VP 16-213) and teniposide (VM 26) in blood plasma. The optimum oxidat
โฆ LIBER โฆ
Flow-injection analysis with a linear pH gradient and diode-array detection applied to organic dyes
โ Scribed by Ch.-H. Fischer; J.G. Rabe
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 554 KB
- Volume
- 284
- Category
- Article
- ISSN
- 0003-2670
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โฆ Synopsis
Ahstraet
Organic dyes were identified using flow-injection analysis with a linear pH gradient and diode-array detection. The identification is based on three independently determined parameters, the two optical absorption spectra measured in acidic and alkaline solution and the pH range of their conversion near the pK values. Binary mixtures can also be analysed. The detection limit of the method was found to be 100 ng for Cnitrophenol as an example. The possibility of quantitative analyses is discussed.
๐ SIMILAR VOLUMES
On-line electrochemical derivatization c
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M.A.J. Van Opstal; J.S. Blauw; J.J.M. Holthuis; W.P. Van Bennekom; A. Bult
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Article
๐
1987
๐
Elsevier Science
๐
English
โ 809 KB