๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Flow-injection analysis with a linear pH gradient and diode-array detection applied to organic dyes

โœ Scribed by Ch.-H. Fischer; J.G. Rabe


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
554 KB
Volume
284
Category
Article
ISSN
0003-2670

No coin nor oath required. For personal study only.

โœฆ Synopsis


Ahstraet

Organic dyes were identified using flow-injection analysis with a linear pH gradient and diode-array detection. The identification is based on three independently determined parameters, the two optical absorption spectra measured in acidic and alkaline solution and the pH range of their conversion near the pK values. Binary mixtures can also be analysed. The detection limit of the method was found to be 100 ng for Cnitrophenol as an example. The possibility of quantitative analyses is discussed.


๐Ÿ“œ SIMILAR VOLUMES


On-line electrochemical derivatization c
โœ M.A.J. Van Opstal; J.S. Blauw; J.J.M. Holthuis; W.P. Van Bennekom; A. Bult ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 809 KB

On-line electrochemical derivatization combined with diode-array u.v./visible detection in flowinjection systems greatly enhances the selectivity. The system is applied for the determination of the antineoplastic agents etoposide (VP 16-213) and teniposide (VM 26) in blood plasma. The optimum oxidat