Flash photolysis of a pyridinium iodide through the charge-transfer band
โ Scribed by Edward M. Kosower; Lars Lindqvist
- Book ID
- 104240372
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 207 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Two bands have been rcsolvcd tn the lrcluj~-pb~~~ spcctn of transrcnt complcxo bctwccn I atoms and ~WC alkyl ioddes. lonkation potential dcpcndcncc and similarrty to compamblu vapor-phase sysfcms indiwtc the clwrgc-transfer miturc of both bands.
In benzene solution, C60 and C7o interact weakly in the ground state with amines having favourable oxidation potentials. Picosecond time-resolved absorption measurements show that on photoexcilation, the weak complexes undergo charge separation to produce ion pairs which in turn undergo fast geminat
Using Laplace transforms, analytical approximations are obtained in a simple way for the probabilities of charge transfer between donor and acceptor states coupled by a bridge. As a test, these are compared with accurate and numerical calculations when the bridge is treated as a standard diatomic Hu