Fixing the Chirality and Trapping the Transition State of Helicene with Atomic Metal Glue
✍ Scribed by Mikael P. Johansson; Michael Patzschke
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 334 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0947-6539
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📜 SIMILAR VOLUMES
An extremely high thermal and chemical stability as well as a unique "out-of-plane" position of the metal atom is shown by the first stable transition metal complexes formed with the proton sponge 1 as the ligand. The properties of these complexes await wide application in catalysis and medicine.
High-temperature adiabatic calorimetry enables accurate determinations to be made of the heat capacity of key materials and, furthermore, is indispensable for development of hightemperature enthalpy standards for differential scanning calorimetry. Adiabatic calorimeters may, however, be used as vers