✦ LIBER ✦

Transition Metal Complexes with the Proton Sponge 4,9-Dichloroquino[7,8-h]quinoline: Highly Twisted Aromatic Systems and an Extreme “Out-of-Plane” Position of the Coordinated Transition Metal Atom

✍ Scribed by Hans-Ulrich Wüstefeld; William C. Kaska; Ferdi Schüth; Galen D. Stucky; Xianhui Bu; Bernt Krebs

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 91 KB
Volume: 40
Category: Article
ISSN: 0044-8249
DOI: 10.1002/1521-3773(20010903)40:17<3182::aid-anie3182>3.0.co;2-j

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✦ Synopsis

An extremely high thermal and chemical stability as well as a unique "out-of-plane" position of the metal atom is shown by the first stable transition metal complexes formed with the proton sponge 1 as the ligand. The properties of these complexes await wide application in catalysis and medicine.